Electrochemistry
Relationship between cell potential and Gibbs' energy change
Cell Thermodynamics:
(i) ΔG = −nF Ecell
(ii) ΔG° = −nF E_{cell}^{o}
(iii) Equilibrium constant \log K=\frac{n\times E_{cell}^{o}}{0.0591}
(iv) Temperature coefficient of cell = \left(\frac{\partial E}{\partial T}\right)_{P}
(v) Enthalpy of reaction inside the cell \Delta H = nFE +nF\left(\frac{\partial E}{\partial T}\right)_{P}
(vi) Entropy change inside the cell, \Delta S = nF\left(\frac{\partial E}{\partial T}\right)_{P}
View the Topic in this Video from 37:04 to 43:07
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