Electrochemistry

Half - cell reactions and Cell reactions


Electrochemical cell representation and half cell and cell reaction:
(I) Metal-Metal combination:

R : Anode  Zn → Zn2+ + 2e
R : Cathode Cu2+ + 2e → Cu
Net Reaction Zn + Cu2+ → Zn2+ + Cu

R : Anode  (Cr → Cr3+ + 3e) × 2
R : Cathode
(Fe2+ + 2e → Fe) × 3
Net Reaction 2Cr + 3Fe2+ → 2Cr3+ + 3Fe
(II) Metal-H2 combination:

R : Anode  Zn → Zn2+ + 2e
R : Cathode 2H+ + 2e → H2
Net Reaction Zn + 2H+ → Zn2+ + H2

R : Anode  H2 → 2H+ + 2e
R : Cathode Cu2+ + 2e → Cu
Net Reaction H2 + Cu2+ → 2H+ + Cu
(III) Metal Non-metal:

R : Anode  Mg → Mg2+ + 2e
R : Cathode Cl2 + 2e → 2Cl
Net Reaction Mg + Cl2 → Mg2+ + 2Cl

R : Anode  2I→ I2 + 2e
R : Cathode 2Ag+ + 2e → 2 Ag
Net Reaction 2I + 2Ag+ → I2 + 2 Ag
(IV) Non-Metal, Non-Metal Combination:

R : Anode  2I→ I2 + 2e
R : Cathode Cl2 + 2e → 2Cl
Net Reaction 2I + Cl2 → I2 + 2Cl

Trick: In the representation of electrochemical cell we have to write Neutral to Neutral and left side oxidation always and right side reduction always.

View the Topic in this Video from 37:50 to 58:20

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