Organic Compounds Containing Nitrogen

General Characteristics and Methods of Preparation of Amines

Hoffmann's Ammonolysis
\tt H_{3}C - CH_{2} - Br \xrightarrow[-HX]{NH_{3}} H_{3}C - CH_{2} - NH_{2} \xrightarrow[]{H_{3}C - CH_{2} - I} \left(CH_{3} - CH_{2}\right)_{2}NH \xrightarrow[]{H_{3}C - CH_{2} - I}\left(C_{2}H_{5}\right)_{3}N\xrightarrow[]{C_{2}H_{5}I} \left(C_{2}H_{5}\right)_{4}NI^{+}
Good yield of Amine (If NH3 is excess)/ Not suitable for Aryl Amine)
Reactivity: R—l > R—Br > R—Cl

Gabriel/Phthalimide Synthesis:

2° & 3° → can't be prepared : Aromatic amine can't prepared

Reduction :

Hoffmann Boroamide Degradation :

Schmidt Reaction

Lossen Reaction

Preparation of aniline:-

Amides, cyanide and Isocyanide:-
Amides preparation

Preparation methods of cyanides:

Preparation methods and properties of Isocyanides:

Preparation of Nitro compounds

Part1: View the Topic in this Video from 0:50 to 55:20

Part2: View the Topic in this Video from 0:54 to 25:04

Part3: View the Topic in this Video from 41:51 to 45:55

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